An Initial Attempt to Evaluate Pesticide Levels in Sligo Creek

This is an attempt to evaluate data from water quality sampling of Sligo Creek by the U.S. Geological Survey on August 23, 1994. The sample was done as part of the study Water Quality in the Potomac River Basin, Maryland, Pennsylvania, Virginia, West Virginia, and the District of Columbia, 1992-96 (USGS Circular 1166), a report released in June 1998. The study found that “a wider variety of pesticides was detected more frequently in small streams than in ground-water samples,” and that “concentrations of pesticides in streams and ground water of the Potomac River Basin are usually not threatening to human health or most ecosystems, based on current standards and understanding.”

However, the lead author of a more recent study released in March 2006 aggregating the findings of the Potomac River basin study with studies of river basins around the country, Pesticides in the Nation’s Streams and Ground Water, 1992–2001 (USGS Circular 1291), which stated that “the potential effects of contaminant mixtures on people, aquatic life, and fish-eating wildlife are still poorly understood and most toxicity information, as well as the water-quality benchmarks used in this study, has been developed for individual chemicals. The common occurrence of pesticide mixtures, particularly in streams, means that the total combined toxicity of pesticides in water, sediment, and fish may be greater than that of any single pesticide compound that is present. Studies of the effects of mixtures are still in the early stages, and it may take years for researchers to attain major advances in understanding the actual potential for effects.”

In the table below, pesticide levels found in Sligo Creek are compared with those in Paint Branch, Cabin John Creek, Accotink Creek, and the standards for pesticides given by the Environmental Protection Agency or other sources when available. Chlorpyrifos is the pesticide which had a higher level in Sligo Creek than the other three reference sites used here, the one time in 1994 Sligo was sampled. The Atrazine level also was comparatively high. None of the pesticides tested for had levels above any known standard for drinking water or aquatic life, though as mentioned little is known about the effects of mixtures of pesticides. If you have any further information please contact [email protected].

Contaminant

Nutrients
Organics
Major Inorganics
Minor and Trace Inorganics
Sligo Creek
at Takoma Park, MD

8/23/1994
(mg/L)
Paint Branch
at College Park, MD

8/24/1994
(mg/L)
Cabin John Creek
at Rockville, MD

8/24/1994
(mg/L)
Accotink Creek
at Annandale, VA

8/23/1994
(mg/L)
Drinking Water Standard
(mg/L)
Aquatic Life Standard
(mg/L)
Common sources
of contaminant
Potential effects from
exposure above standard
2,6-Diethylaniline
< 0.000003
< 0.000003
< 0.000003
< 0.000006
x
x
Herbicide runoff
x
2-Chloro-4-isopropylamino-6-amino-s-triazine(aka CIAT)
< 0.000002
< 0.000002
< 0.000002
< 0.000005
x
x
Herbicide runoff
Irritation of eyes, skin, respiratory tract
Alachlor
< 0.000002
< 0.000002
< 0.000002
< 0.000009
0.0021
x
Runoff from herbicide used on row crops
Trade name: Lasso
Eye, liver, kidney or spleen problems;
anemia; increased cancer risk
alpha-HCH
< 0.000002
< 0.000002
< 0.000002
< 0.000007
0.00000269
x
Insecticide runoff
Recognized carcinogen; suspected liver toxicant
alpha-HCH-d6
109 % recovery
104 % recovery
92.7 % recovery
95.0 % recovery
x
x
x
x
Ammonia
0.030
0.090
0.020
0.050
x
(2.0-8.0)8
Cleaners and fertilizers; occurs naturally in small amounts
Suspected toxicant of nerves, respiratory system, reproductive system, skin and liver
Ammonia plus organic nitrogen
< 0.20
0.20
< 0.20
0.30
x
x
x
x
Atrazine
0.000011
< 0.000001
0.000008
< 0.000017
0.0031
0.0024
Runoff from herbicide used on row crops
Trade names: AAtrex, Gesaprim
Cardiovascular system
or reproductive problems
Azinphos-methyl
< 0.000001
< 0.000001
< 0.000001
< 0.00005
x
0.000014
Insecticide runoff
Trade names: Guthion, Gusathion
Suspected neurotoxicant, respiratory toxicant
Benfluralin
< 0.000002
< 0.000002
< 0.000002
< 0.000013
x
x
Herbicide runoff
Trade names: Balan, Benefin, Bonalan
Suspected cardiovascular and blood toxicant
Bicarbonate
80
32
70
37
x
x
x
x
Butylate
< 0.000002
< 0.000002
< 0.000002
< 0.000008
One-day: 2
Ten-day: 2
Life-time:0.43
x
Herbicide runoff
Trade names: Sutan, Genate Plus
Suspected neurotoxicant; toxic to fish
Calcium
29.0
13.0
25.0
11.0
x
x
x
x
Carbaryl
Estimated
0.000120
Estimated
0.000026
Estimated
0.000086
0.000190
One-day: 1
Ten-day: 1
Life-time:0.73
x
Insecticide runoff
Trade names: Sevin, Savit
Suspected carcinogen, toxicant of blood, endocrine system, muscoloskeletal system, nerves, reproductive system, developing children
Carbofuran
< 0.000003
< 0.000003
< 0.000003
< 0.000013
0.041
x
Leaching of soil fumigant; used on rice and alfalfa
Trade names: Furadan, Curaterr
Problems with blood, nervous system,
or reproductive system
Chloride
36.0
21.0
47.0
16.0
2502
x
x
x
Chlorpyrifos
0.000019
< 0.000004
0.000009
0.000014
One-day:0.03
Ten-day:0.03
Life-time:0.023
0.054
Insecticide runoff
Trade names: Dursban, Lorsban
Suspected toxicant of nervous, endocrine, and reproductive systems
ranked as one of the most hazardous compounds to ecosystems
cis-Permethrin
< 0.000005
< 0.000005
< 0.000005
< 0.000013
x
x
Insecticide runoff
Trade names: Ambush, Astro, Pounce, Pramex, Pertox, Ambushfog, Kafil, Perthrine, Picket, Picket G, Dragnet, Talcord, Outflank, Stockade, Eksmin, Coopex, Peregin, Stomoxin, Stomoxin P, Qamlin, Corsair, Tornade
x
Cyanazine
< 0.000004
< 0.000004
< 0.000004
< 0.000013
One-day: 0.1
Ten-day: 0.1
Life-time:0.0013
x
Pesticide runoff
Trade names: Bladex, Fortrol
Adverse effects on developing children
DCPA
Estimated
0.000001
< 0.000002
< 0.000002
< 0.000004
x
x
Herbicide runoff
Trade name: Dacthal
Suspected carcinogen
DDE, p,p’
< 0.000006
< 0.000006
< 0.000006
< 0.000010
0.00014,7
0.0000017
Insecticide runoff
Recognized carcinogen; suspected neurotoxicant, liver and endocrine toxicant.
Ranked as one of the most hazardous compounds to ecosystems
Diazinon
0.000044
< 0.000002
0.000016
0.000610
One-day:0.02
Ten-day:0.02
Life-time:0.00063
0.00014
Insecticide runoff
Suspected toxicant of liver, nervous system, reproductive system, skin, cardiovascular system, developing children
Diazinon-d10
128 % recovery
131 % recovery
133 % recovery
167 % recovery
x
x
x
x
Dieldrin
< 0.000001
< 0.000001
< 0.000001
< 0.000008
One-day:0.03
Ten-day:0.033
0.0000565
Insecticide runoff
Trade names: Panoram D-31, Octalox
Probable human carcinogen
Disulfoton
< 0.00002
< 0.00002
< 0.00002
< 0.00006
x
0.0000377
Insecticide runoff
Trade names: Disyston, Di-Syston, Frumin AL, Solvirex, Ethylthiodemeton
Suspected toxicant of nerves, respiratory system, developing children
EPTC
< 0.000002
< 0.000002
< 0.000002
< 0.000005
x
x
Herbicide runoff
Trade name: Eptam
Recognized developmental toxicant; suspected toxicant of skin, liver, nerves, blood, reproductive system
Ethalfluralin
< 0.000004
< 0.000004
< 0.000004
< 0.000013
x
x
Herbicide runoff
Trade names: Sonalan, Curbit
Suspected carcinogen
Ethoprop
< 0.000003
< 0.000003
< 0.000003
< 0.000012
x
x
Insecticide runoff
Trade names: Mocap, Prophos
Recognized carcinogen; suspected neurotoxicant
Fonofos
< 0.000003
< 0.000003
< 0.000003
0.000021
One-day:0.02
Ten-day:0.02
Life-time:0.013
x
Insecticide runoff
Trade name: Dyfonate
Suspected neurotoxicant
Fluoride
0.2
< 0.1
0.1
0.1
2.02
x
x
Suspected toxicant of liver, kidney, nerves, musculoskeletal, and respiratory systems
Iron
0.1
0.16
0.14
0.32
0.32
x
x
x
Lindane
< 0.000004
< 0.000004
< 0.000004
< 0.000011
0.00021
0.000955
Runoff/leaching from insecticide
used on cattle, lumber, gardens
Liver or kidney problems
Linuron
< 0.000002
< 0.000002
< 0.000002
< 0.000039
x
0.014
Herbicide runoff
Trade names: Lorox, Linex, Sarclex
Recognized developmental toxicant; suspected carcinogen, toxicant of blood and endocrine system
Magnesium
6.20
4.00
9.50
3.10
x
x
x
x
Malathion
< 0.000005
< 0.000005
< 0.000005
< 0.000014
One-day: 0.2
Ten-day: 0.2
Life-time:0.13
x
Insecticide runoff
Trade names: maldison, malathon, Cythion
Suspected toxicant of blood, cardiovascular, endocrine, liver, immune, nervous, and reproductive systems
Manganese
0.028
0.03
0.026
0.079
0.052
x
x
Suspected toxicant of nerves, liver, reproductive and respiratory systems
Methyl Parathion
< 0.000006
< 0.000006
< 0.000006
< 0.000035
One-day: 0.3
Ten-day: 0.3
Life-time:0.0023
x
Insecticide runoff
Trade name: Penncap-M
Suspected toxicant of blood, cardiovascular, endocrine, liver, immune, nervous, and reproductive systems
Metolachlor
0.000011
0.000004
0.000100
0.000010
One-day: 2
Ten-day: 2
Life-time:0.13
0.014
Herbicide runoff
Trade names: Dual, Pennant
Suspected carcinogen and toxicant of cardiovascular system, blood
Metribuzin
< 0.000004
< 0.000004
< 0.000004
< 0.000012
One-day: 5
Ten-day: 5
Life-time:0.23
x
Herbicide runoff
Trade names: Lexone, Sencor
Suspected toxicant of kidneys, liver, endocrine system, developing children
Molinate
< 0.000004
< 0.000004
< 0.000004
< 0.000007
x
0.217
Herbicide runoff
Trade name: Ordram
Suspected endocrine, developmental, cardiovascular, blood, reproductive and neurotoxicant and carcinogen
Napropamide
< 0.000003
< 0.000003
< 0.000003
< 0.000010
x
x
Herbicide runoff
Trade name: Devrinol
x
Nitrite (measured as Nitrogen)
0.01
0.14
< 0.01
0.01
11
x
Runoff from fertilizer use; leaching from septic tanks, sewage; erosion of natural deposits
Infants below the age of six months who drink water containing nitrate in excess of the MCL could become seriously ill and, if untreated, may die. Symptoms include shortness of breath and blue-baby syndrome.
Nitrite plus nitrate
1.40
2.10
1.60
0.68
x
x
x
x
Orthophosphate
0.02
< 0.01
0.01
0.02
x
x
x
x
Parathion
< 0.000004
< 0.000004
< 0.000004
< 0.000022
x
0.0000139
Insecticide runoff
Trade names: Roethyl-P, Alkron, Panthion, Phoskil
Suspected carcinogen, toxicant of blood, skin, endocrine, nerves, respiratory and reproductive systems
Pebulate
< 0.000004
< 0.000004
< 0.000004
< 0.000009
x
x
Herbicide runoff
Trade name: Tillam
Suspected neurotoxicant
Pendimethalin
< 0.000004
< 0.000004
< 0.000004
< 0.000018
x
x
Herbicide runoff
Trade names: Prowl, Stomp
Suspected carcinogen, liver and endocrine toxicant
Phorate
< 0.000002
< 0.000002
< 0.000002
< 0.000011
x
0.00057
Insecticide runoff
Trade names: Thimet, Granutox, Geomet, Rampart
Suspected neurotoxicant
Phosphorus
0.03
< 0.01
0.01
0.03
x
x
x
x
Potassium
3.80
2.70
3.30
3.00
x
x
x
x
Prometon
0.00004
< 0.00002
< 0.00002
0.00008
One-day: 0.2
Ten-day: 0.2
Life-time: 0.13,4
x
Herbicide runoff
Trade names: Gesagram, prometone
x
Propachlor
< 0.000007
< 0.000007
< 0.000007
< 0.000015
One-day: 0.5
Ten-day: 0.5
Life-time: 0.093, 4
x
Herbicide runoff
Trade names: Ramrod, propachlore
Recognized carcinogen; suspected respiratory, skin, sense organ, developmental, and neurotoxicant
Propanil
< 0.000004
< 0.000004
< 0.000004
< 0.000016
x
x
Herbicide runoff
Trade names: Stam, Stampede, Wham, Surcopur, Prop-Job
Suspected toxicant of blood, skin, liver, nerves, respiratory, and endocrine systems
Propargite
< 0.00001
< 0.00001
< 0.00001
< 0.00001
x
0.0097
Insecticide runoff
Trade names: Comite, Omite, Ornamite
Recognized carcinogen, developmental toxicant
Propyzamide
< 0.000003
< 0.000003
< 0.000003
< 0.000009
x
x
Herbicide runoff
Recognized carcinogen; suspected endocrine toxicant
Silica
9.80
9.30
13.0
10.0
x
x
x
x
Simazine
0.000014
< 0.000005
0.000025
0.000016
0.0041
x
Herbicide runoff
Trade names: Aquazine, Princep, Gesatop
Problems with blood
Sodium
14.0
13.0
19.0
9.80
x
x
x
x
Sulfate
15.0
13.0
16.0
8.0
2502
x
x
x
Tebuthiuron
< 0.00001
< 0.00001
< 0.00001
< 0.00001
One-day: 3
Ten-day: 3
Life-time: 0.53,0.14
0.0014
Herbicide runoff
Trade names: Spike, Perflan
Suspected toxicant of developing children, nervous system
Terbacil
< 0.000007
< 0.000007
< 0.000007
< 0.000030
One-day: 0.3
Ten-day: 0.3
Life-time: 0.093,0.14
x
Herbicide runoff
Trade name: Sinbar
Recognized developmental toxicant; suspected liver toxicant
Terbufos
< 0.00001
< 0.00001
< 0.00001
< 0.00001
One-day:0.005
Ten-day:0.005
Life-time: 0.00093
x
Insecticide runoff
Trade names: Contraven, Counter, Pilarfox
Suspect neurotoxicant
Terbuthylazine
147 % recovery
100 % recovery
99 % recovery
120 % recovery
x
x
x
x
Thiobencarb
< 0.000002
< 0.000002
< 0.000002
< 0.000008
x
0.287
Herbicide runoff
Trade names: Bolero, Saturn, Benthiocarb, Abolish
Suspected neurotoxicant
Triallate
< 0.000001
< 0.000001
< 0.000001
< 0.000008
x
x
Herbicide runoff
Trade names: Far-Go, Avadex BW, Tri-allate
Suspected carcinogen, neurotoxicant
Trifluralin
< 0.000002
< 0.000002
< 0.000002
< 0.000012
0.014
0.00014
Herbicide runoff
Trade names: Treflan, Trinin, Elancolan
Suspected carcinogen, toxicant of blood, developing children, endocrine, skin, liver, reproductive and immune systems

Sources of Standards

1National Primary Drinking Water Standard

2National Secondary Drinking Water Standard

32004 Edition of the Drinking Water Standards and Health Advisories

4Summary of Compound Detections and Concentrations
(A chapter from USGS Circular 1166: Water Quality in the Potomac River Basin, Maryland, Pennsylvania, Virginia, West Virginia, and the District of Columbia, 1992-96)

5Maryland State Numerical Criteria for Toxic Substances in Surface Waters

6EPA: Pesticides – Specific Chemical Fact Sheets

7Water Quality Benchmarks
(Appendix 3 from USGS Circular 1291: Pesticides in the Nation’s Streams and Ground Water, 1992–2001 (published March 2006)

8EPA: Aquatic Life Water Quality Criteria

9EPA: Current National Recommended Water Quality Criteria


Other Water Quality Parameters Measured

Parameter Sligo Creek
at Takoma Park, MD

8/23/1994
Paint Branch
at College Park, MD

8/24/1994
Cabin John Creek
at Rockville, MD

8/24/1994
Accotink Creek
at Annandale, VA

8/23/1994
Acid neutralizing capacity
68 mg/L as CaCO3
29 mg/L as CaCO3
60 mg/L as CaCO3
32 mg/L as CaCO3
Alkalinity
66 mg/L as CaCO3
26 mg/L as CaCO3
57 mg/L as CaCO3
30 mg/L as CaCO3
Barometric pressure
763 mm Hg
767 mm Hg
760 mm Hg
762 mm Hg
Dissolved oxygen
9.5 mg/L
9.9 mg/L
8.6 mg/L
8.2 mg/L
Instantaneous discharge
3.3 cfs
7.6 cfs
0.91 cfs
13 cfs
pH, field
7.6
7.2
7.3
6.7
pH, laboratory
6.6
7.2
7.8
7.0
Residue on evaporation
173 mg/L
101 mg/L
201 mg/L
98 mg/L
Sample volume
913 mL
893 mL
874 mL
925 mL
Specific conductance, field
318 µS/cm 25 degC
186 µs/cm 25 degC
330 µs/cm 25 degC
142 µs/cm 25 degC
Specific conductance, laboratory
305 µS/cm 25 degC
188 µS/cm 25 degC
329 µS/cm 25 degC
143 µS/cm 25 degC
Suspended sediment concentration
4 mg/L
3 mg/L
4 mg/L
x
Temperature, air
21.0 C
20.0 C
25.5 C
20.5 C
Temperature, water
21.0 C
17.5 C
20.0 C
19.5 C